Techniques to create low K ILD for BEOL

ABSTRACT

One aspect of the present subject matter relates to a method for forming an interlayer dielectric (ILD). In various embodiments of the method, an insulator layer is formed, at least one trench is formed in the insulator layer, and a metal layer is formed in the at least one trench. After the metal layer is formed, voids are formed in the insulator layer. One aspect of the present subject matter relates to an integrated circuit. In various embodiments, the integrated circuit includes an insulator structure having a plurality of voids that have a maximum size, and a metal layer formed in the insulator structure. The maximum size of the voids is larger than the minimum photo dimension of the metal layer such that a maximum-sized void is capable of extending between a first and second metal line in the metal layer. Other aspects are provided herein.

CROSS REFERENCE TO RELATED APPLICATION

This application is related to the following commonly assigned U.S.patent application which is herein incorporated by reference in itsentirety: “Low K Interconnect Dielectric Using Surface Transformation,”Ser. No. 10/106,915, filed on Mar. 25, 2002.

TECHNICAL FIELD

This disclosure relates generally to integrated circuits, and moreparticularly, to integrated circuit dielectrics.

BACKGROUND

The semiconductor industry continuously strives to reduce the size andcost of integrated circuits. With the progressive scaling of featuresize and Vdd, there has been a continuous drive and challenge to reduceinterconnect capacitance to improve performance, to contain noise and toreduce active power.

One method for measuring the performance of an integrated circuit usesthe maximum clock speed at which the circuit operates reliably, whichdepends on how fast transistors can be switched and how fast signals canpropagate. One particular problem confronting the semiconductor industryis that, as integrated circuit scaling continues, the performanceimprovement is limited by the signal delay time attributable tointerconnects in the integrated circuit. According to one definition,integrated circuit interconnects are three-dimensional metal lines withsubmicrometer cross sections surrounded by insulating material. Onedefinition of an interconnect delay is the product of the interconnectresistance (R) and the parasitic capacitance (C) for the interconnectmetal to the adjacent layers. Because of the progressive scaling, theparasitic capacitance (C) has significantly increased due to closerrouting of wires, and the interconnect resistance (R) has significantlyincreased due to a continuous reduction of the wire section.

The following approximations for various generations of integratedcircuit technology illustrates this problem. For example, the delay in0.7 μm technology is about 500 ps, in which about 200 ps seconds areattributable to gate delays and about 300 ps are attributable tointerconnect delays. The delay in 0.18 μm technology is about 230 ps, inwhich about 30 ps are attributable to gate delays and about 200 ps areattributable to interconnect delays. As integrated circuit scalingcontinues, it is desirable to lower the interconnect RC time constant byusing metals with a high conductivity. One high conductivity metal usedto lower the RC constant is copper. The use of copper in 0.18 μmtechnology improves the interconnect delays to about 170 ps. However,even though the delay attributable to the gates continues to decrease asscaling continues beyond the 0.18 μm technology, the overall delayincreases significantly because the interconnect delay is significantlyincreased. It has been estimated that as much as 90 percent of thesignal delay time in future integrated circuit designs may beattributable to the interconnects and only 10 percent of the signaldelay may be attributable to transistor device delays. As such, it isdesirable to lower the interconnect RC time constant by using materialswith a low dielectric constant (K) between co-planer and inter-planerinterconnects.

Considerable progress has been made in recent years towards developinglower K interlayer dielectric (ILD) using inorganic and organicmaterials. For example, low-K dense materials are available having a Kin a range between 2.5 and 4.1. Additionally, improved processes havebeen developed using silicon dioxide (SiO₂) (K=4) and Polyimide (K=3.7).SiO₂-based inorganic dielectrics have been preferred because theyprovide the thermal and mechanical stability and reliability requiredfor multilevel interconnect integration requirements.

One direction for developing low-K dielectrics incorporates air intodense materials to make them porous. The dielectric constant of theresulting porous material is a combination of the dielectric constant ofair (K≈1) and the dielectric constant of the dense material. As such, itis possible to lower the dielectric constant of a low-k dense materialby making the dense material porous. Some of the recent developments inILDs include fluorinated oxide (K=3.5), Spin-On-Glass HydrogenSilisequioxane (SOG-HSQ) (K=2.7-3.3) and porous siloxane based polymer,also known as Nanoglass (K=2.2-2.3). The fluorination of dielectriccandidates, such as Teflon®, achieve a K of about 1.9.

Current research and development is attempting to achieve a dielectricmaterial with a K value around 2 and lower, by incorporating controlledporosity or voids (K=1) in an otherwise dense and mechanically andthermally stable material that is compatible with the interconnectmetallurgy and which can be readily integrated with the currentlyadopted back-end-of-the-line (BEOL) processing and tooling.

Xerogels and Aerogels introduce voids of 5-10 nm in the SOG-HSQmaterials to achieve K values less than 2. However, the materialcompositions and processing are not very reproducible due to theinherent presence of large amount of liquid solvents and non-solventsthat need to be removed to create voids and due to shrinkages resultingin internal stress and cracking.

Processes to form porous polymers have been shown in previous work byFarrar (Method Of Forming Foamed Polymeric Material For An IntegratedCircuit, U.S. Pat. No. 6,077,792; Method Of Forming Insulating MaterialFor An Integrated Circuit And Integrated Circuits Resulting From Same,U.S. Ser. No. 09/480,290, filed Jan. 10, 2000; Polynorbornene FoamInsulation For Integrated Circuits, Ser. No. 09/507,964, filed Feb. 22,2000). However, there are some applications where it is desirable to useinorganic porous structures.

The demands placed upon a process for producing a porous structurebecomes more stringent as photolithographic dimensions are decreased.Currently, in a damascene metal process, the pores are formed in a layerof insulator prior to etching. Thus, the maximum pore size must be lessthan the minimum photo dimension, else some of the pores will be locatedbetween and connect two trenches. When the metal is deposited in thedamascene trenches, the metal fills the pore and forms a short betweenthe lines in two trenches. Thus, if the pores are formed before themetal layer is defined, the pores size distribution should shrink in thesame ratio as the minimum feature size. These demands are illustrated inFIGS. 1 and 2.

FIG. 1 illustrates relatively small pores 102 and metal lines 104 and106 formed in an insulator 108 using a damascene process. The pores 102are smaller than the photo dimension of the lines 104 and 106. The pores102 are formed before the metal is deposited, such that the metal 110flows into some of the pores. However, the pores are small enough sothat a short does not form between the metal lines.

FIG. 2 illustrates relatively large pores 202 and metal lines 204 and206 formed in an insulator 208 using a damascene process. At least someof the pores 202 are larger than the photo dimension of the lines 204and 206. The pores are formed before the metal is deposited, such thatthe metal flows into some of the pores. The metal 210 is capable offlowing through a pore and forming a short between the metal lines.

Therefore, there is a need in the art to provide an improved low-Kdielectric insulator for interconnects.

SUMMARY

The above mentioned problems are addressed by the present subject matterand will be understood by reading and studying the followingspecification. The present subject mater relates to improved interlayerdielectric (ILD) devices and methods of formation. The present subjectmatter provides methods for forming voids in the ILD after the metallayer has been formed so as to alleviate the demands placed upon aprocess for producing a porous structure. The present subject matter isparticularly useful as photolithographic dimensions continue todecrease.

One aspect of the present subject matter relates to a method for formingan interlayer dielectric (ILD). According to various embodiments of themethod, an insulator is formed, at least one trench is formed in theinsulator, and a metal layer is formed in the at least one trench. Voidsare formed in the insulator layer after the metal layer is formed.

According to various embodiments of the method, a multiphase matrix isformed as an insulator layer. At least one trench is formed in theinsulator layer and a metal layer is then formed in the at least onetrench. At least one phase is at least partially removed from themultiphase matrix to form voids in the insulator layer.

According to various embodiments of the method, an insulator layer isformed, at least one trench is formed in the insulator, and a metallayer is formed in the at least one trench. After forming the metallayer, an inert gas is implanted and the insulator layer is annealed inan inert ambient to form a number of voids in the insulator layer.

One aspect of the present subject matter relates to an integratedcircuit. According to various embodiments, the integrated circuitincludes an insulator structure having a plurality of voids that have amaximum size, and a metal layer formed in the insulator structure. Themetal layer has a minimum photo dimension. The maximum size of the voidsis larger than the minimum photo dimension of the metal layer. Thus, amaximum-sized void is capable of extending between a first metal lineand a second metal line in the metal layer.

These and other aspects, embodiments, advantages, and features willbecome apparent from the following description of the present subjectmatter and the referenced drawings.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 illustrates relatively small pores and metal lines formed in adamascene process.

FIG. 2 illustrates relatively large pores and metal lines formed in adamascene process.

FIG. 3 illustrates an integrated circuit in which relatively large poresare formed after the metal lines are formed according to variousembodiments of the present subject matter.

FIG. 4 illustrates a method for forming an interlayer dielectric (ILD)according to various embodiment of the present subject matter.

FIG. 5 illustrates a method for forming an ILD according to variousembodiment of the present subject matter.

FIG. 6 illustrates a method for forming an ILD according to variousembodiment of the present subject matter.

FIG. 7 illustrates a method for forming an ILD using a first processscheme according to various embodiments of the present subject matter.

FIG. 8 illustrates a method for forming an ILD using a first processscheme according to various embodiments of the present subject matter.

FIG. 9 illustrates a method for forming an ILD using a second processscheme according to various embodiments of the present subject matter.

FIG. 10 illustrates a method for creating a gas phase in an insulatorstructure according to various embodiments of the present subjectmatter.

FIG. 11 illustrates a method for creating a gas phase in an insulatorstructure according to various embodiments of the present subjectmatter.

FIG. 12 illustrates a method for forming an ILD using a second processscheme according to various embodiments of the present subject matter.

FIGS. 13A through 13I illustrate an example of forming an ILD using thefirst process scheme.

FIGS. 14A through 14I illustrate an example of forming an ILD using thesecond process scheme.

FIG. 15 is a simplified block diagram of a high-level organization ofvarious embodiments of an electronic system according to the presentsubject matter.

FIG. 16 is a simplified block diagram of a high-level organization ofvarious embodiments of an electronic system according to the presentsubject matter.

DETAILED DESCRIPTION

The following detailed description refers to the accompanying drawingswhich show, by way of illustration, specific aspects and embodiments inwhich the present subject matter may be practiced. These embodiments aredescribed in sufficient detail to enable those skilled in the art topractice the present subject matter. Other embodiments may be utilizedand structural, logical, and electrical changes may be made withoutdeparting from the scope of the present subject matter. The followingdetailed description is, therefore, not to be taken in a limiting sense,and the scope of the present subject matter is defined only by theappended claims, along with the full scope of equivalents to which suchclaims are entitled.

The present subject matter introduces micro-voids and/or nano-voidswithin a conventionally processed ILD (such as oxides, fluorinatedoxide, SOG-HSQ and the like) to achieve K values in the range of 2-3 orlower without adversely affecting thermal and mechanical stability whenthe pores are formed after the film is deposited. The present subjectmatter introduces pores into the dielectric after the metal layer isdefined, as illustrated below with respect to FIG. 3.

FIG. 3 illustrates an integrated circuit in which relatively large pores302 are formed in the insulator 308 after the metal lines 304 and 306are formed according to various embodiments of the present subjectmatter. The pores 302 are capable of being larger than the photodimension of the lines 304 and 306 because they are formed after themetal is deposited. As such, no short occurs even if the pores extendfrom one line to another line because air is a good insulator.

As is described below, a number of process schemes are used in variousembodiments of the present subject matter. In a first scheme, theinsulator is a multi-phase structure. After the insulator is patterned,at least one of the phases is removed leaving the matrix phase intact.The intact matrix phase continues to provide structural rigidity and thespaces where the second (or multiple phases in the case of three phaseor more complex structure) are now filled with air or other gas. Asecond process scheme introduces a gas phase (e.g. an inert gas such ashelium (He), argon (Ar), or nitrogen (N₂)) into the insulator after itis in the solid state. The introduced gas phase also can include air. Invarious embodiments of this scheme, an inert gas (e.g. He, Ar, N₂) isimplanted into the post-processed insulator to create stable voids(microvoids or nanovoids) resulting in a two-phase insulator-gas (void)structure.

FIG. 4 illustrates a method for forming an interlayer dielectric (ILD)according to various embodiment of the present subject matter. Accordingto the illustrated method 412, an insulator layer is formed at 414,trenches are formed in the insulator layer at 416, and a metal layer isformed in the trenches at 418. According to various embodiments, theinsulator layer is formed from an inorganic material. One of ordinaryskill in the art will understand, upon reading and comprehending thisdisclosure, that the metal layer is appropriately connected to variousdevices to form an integrated circuit. After the metal layer is formedat 418, voids are formed in the insulator layer at 420. Because thevoids are formed after the metal layer is formed, the voids that arelarger than the photo dimension of the metal layer will not cause ashort between metal lines.

FIG. 5 illustrates a method for forming an ILD according to variousembodiment of the present subject matter. According to the illustratedmethod 512, an insulator layer is formed at 514, trenches are formed inthe insulator layer at 516, and a metal layer is formed in the trenchesat 518. At 522, the process returns to 514 if additional metal layersare to be formed. Thus, an ILD structure having more than one metallayer is capable of being formed. If no additional layers are to beformed, the process proceeds to 520 where voids are formed in one ormore of the insulator layers. In this embodiment, voids are capable ofbeing formed in more than one insulator layer after the last metal layerhas been formed.

FIG. 6 illustrates a method for forming an ILD according to variousembodiment of the present subject matter. According to the illustratedmethod 612, an insulator layer is formed at 614, trenches are formed inthe insulator layer at 616, and a metal layer is formed in the trenchesat 618. The process proceeds to 620 where voids are formed in theinsulator layer. At 622, the process returns to 614 if additional metallayers are to be formed. Thus, an ILD structure having more than onemetal layer is capable of being formed. In this embodiment, the voidsare formed after each metal layer is formed as the ILD structure isbeing built.

One of ordinary skill in the art will understand, upon reading andcomprehending this disclosure, that the methods illustrated in FIGS. 5and 6 can be combined to intermediately form voids in one or more of theinsulator layers as the ILD structure is being built. Thus, for example,voids are capable of being formed in the first and second insulatorlayers after the second metal level is formed, are capable of beingformed in the third insulator layer after the third metal level isformed, and are capable of being formed in the fourth insulator layerafter the fourth metal level is formed.

Process Scheme 1: Remove Phase(s) from Multi-Phase Insulator Structure.

FIG. 7 illustrates a method for forming an ILD using a first processscheme according to various embodiments of the present subject matter.According to the illustrated method 712, an insulator layer having amultiphase structure is formed at 714, trenches are formed in theinsulator layer at 716, and a metal layer is formed in the trenches at718. After the metal layer is formed at 718, voids are formed in theinsulator layer at 720 by removing (or partially removing) one or morephases from the multiphase structure. Because the voids are formed afterthe metal layer is formed, the voids that are larger than the photodimension of the metal layer will not cause a short between metal lines.

FIG. 8 illustrates a method for forming an ILD using a first processscheme according to various embodiments of the present subject matter.According to the illustrated method 812, an insulator having amultiphase structure is formed at 814. In various embodiments, a mixtureof glass particles and carbon particles is formed or otherwise providedat 822. In various embodiments, the glass particles have a low-meltingtemperature, such as that provided by fritted glass. In variousembodiments, the carbon particles are provided as graphite particles. At824, the ratio of the carbon particles to the glass particles is capableof being varied or selected to achieve a desired pore density. At 826,the particle size of the carbon is capable of being varied or selectedaccording to the desired thickness of the insulator layer. At 828, themixture is heated to above the softening temperature of the glass untilthe glass flows and forms a continuous matrix phase that contains carbonparticles.

Metal lines are formed in the insulator using a damascene process.Trenches are formed in the insulator at 816, and a metal layer isdeposited in the trenches at 818. At 820, the resulting structure isexposed to a high temperature oxygen (O₂) containing environment. Theoxygen diffuses through the glass matrix, oxidizes with carbon, andforms carbon dioxide (CO₂) voids in the insulator structure. Thus, thecarbon phase of the multiphase structure is at least partially removeddue to the diffusion of oxygen into the structure. The time of exposureis capable of being varied or selected at 830, the temperature of theenvironment is capable of being varied or selected at 832, and the O₂concentration is capable of being varied or selected at 834.

The diffusion distance of the oxygen through the glass and between thecarbon particles is minimal because the maximum size of the carbonparticles is equal to the thickness of the film to be formed such thatmany particles extend through the film. A rapid thermal anneal (RTA) isused in various embodiments to minimize the temperature exposure to theunderlying device structure. In various embodiments, the RTA includes alaser anneal. In various embodiments, the RTA includes a plasma anneal.In various embodiments, the elevated temperature of the environment isin a range from 400 to 500° C., or in various sub-ranges within 400 to500° C.

Process Scheme 2: Create Gas Phase in Insulator Structure.

FIG. 9 illustrates a method for forming an ILD using a second processscheme according to various embodiments of the present subject matter.According to the illustrated method 912, an insulator layer is formed at914, trenches are formed in the insulator layer at 916, and a metallayer is formed in the trenches at 918. After the metal layer is formedat 918, voids are formed in the insulator layer at 920 by creating a gasphase in the insulator layer. Because the voids are formed after themetal layer is formed, the voids that are larger than the photodimension of the metal layer will not cause a short between metal lines.

FIG. 10 illustrates a method for creating a gas phase in an insulatorstructure according to various embodiments of the present subjectmatter. The illustrated method is represented as 1020, and generallycorresponds to element 920 in FIG. 9. According to the illustratedmethod 1020, an inert gas is implanted into the insulator layer at 1036,and the resulting structure is annealed at 1038.

FIG. 11 illustrates a method for creating a gas phase in an insulatorstructure according to various embodiments of the present subjectmatter. The illustrated method is represented as 1120, and generallycorresponds to element 920 in FIG. 9. According to the illustratedmethod 1120, helium (He) (or another inert or non-reacting gas such asargon (Ar), nitrogen (N₂) and the like) is implanted into the insulatorlayer at 1136, and the resulting structure is annealed at 1138. Heliumis used herein to simplify the disclosure. One of ordinary skill in theart will understand, upon reading and comprehending this disclosure,that the present subject matter is not limited to helium. Voids, such asnano-voids, are formed when implant induced vacancies and helium migrateand combine during the post-implant anneal.

FIG. 12 illustrates a method for forming an ILD using a second processscheme according to various embodiments of the present subject matter.The illustrated method is represented as 1220, and generally correspondsto element 920 in FIG. 9. According to the illustrated method 1220,helium (He) is implanted into the insulator layer at 1236, and theresulting structure is annealed at 1238.

The size and distribution of the voids are capable of being controlledby varying or selecting an implant dose at 1240 and an implant energy at1242. Stable geometries are capable of being obtained by appropriatelyvarying or selecting the post-implant annealing parameters, such astemperature at 1246, time at 1248, ambient (such as He, N₂, Ar and thelike) at 1250, annealing tools at 1252, and annealing methodology at1254.

In various embodiments, after the insulator is processed, a heavy doseof an inert gas is implanted in the processed insulator, and theresulting structure is annealed. For example, in various embodiments, adose of helium (He) in excess of 2×10¹⁵/cm² is implanted. Stablenano-cavities or nano-voids are generated inside of the ILD material.The voids are formed when implant induced vacancies and helium migrateand combine during the post-implant anneal.

The size and distribution of these voids are capable of being varied byvarying the implant dose. Stable geometries are capable of beingobtained by optimizing the post-implant annealing parameters, such asannealing temperature, time, ambient, annealing tools, and methodology.Multiple layers of these nanovoids are capable of being formed andstabilized by successive implants at different implant energies byplacing helium and vacancy clusters at different depths of the materialin which helium is ion implanted and the material is appropriatelyannealed.

Multiple layers of nano-voids, arranged with a desired geometry, arecapable of being generated by implanting the inert gas at differentdepths of ILD by varying the implant energy and adjusting the dose andannealing tools and parameters. It has been shown that single andmultiple layers of stable micro/nano cavities can be formed in siliconmaterial by implanting a dose of helium greater than or equal to 2×10¹⁵at different implant energies followed by an appropriate anneal in aninert ambient. Stable multiple layers of spherical cavities, of 10 to 90nm in diameters of similar shape, have been formed in silicon within thelayer. The distance of separation between layers is from 110 nm to 120nm.

The ILD layer is first produced by a back-end-of-line (BEOL) processingof silicon technology. A first layer of voids (helium or other ions) andassociated vacancy cluster) is generated at a desired depth byappropriately selecting the dose and energy of the helium implant. Theimplanted structure is annealed in an inert ambient with an appropriatethermal budget (e.g. time, temperature and the like) to control andstabilize the geometry and distribution of the voids. In variousembodiments, the inert ambient includes nitrogen. In variousembodiments, the inert ambient includes argon.

In various embodiments, the thermal budget is contained and controlledby using appropriate rapid thermal annealing. In various embodiments,the thermal budget is contained and controlled by using laser pulseannealing. In various embodiments, the thermal budget is contained andcontrolled by using plasma annealing at a relatively low temperature.

Multiple layers of stable voids are capable of being formed at a desireddepth inside the ILD material by repeating the implant and annealingwith an appropriate implant energy. As described in the United StatesPatent Application entitled “Low K Interconnect Dielectric Using SurfaceTransformation,” Ser. No. 10/106,915, filed on Mar. 25, 2002, which waspreviously incorporated by reference, a stable void fraction of greaterthan 0.5 is capable of being readily targeted within a SiO₂ ILD layer.An effective K value of ILD less than or equal to 1.5 is capable ofbeing achieved by incorporating stable nan-voids in SiO₂ ILD. Thereforeinter and intra-layer capacitance of BEOL interconnects are capable ofbeing dramatically reduced and chip performance is capable of beingsignificantly improved.

PROCESS EXAMPLES

Process examples are provided below to illustrate both the ProcessScheme 1 and the Process Scheme 2. One of ordinary skill in the art willunderstand, upon reading and comprehending this disclosure, that theseexamples illustrate embodiments of the present subject matter, and thatother structural embodiments and method embodiments are capable of beingderived from these examples.

These examples relate to the construction of a four level metalstructure, as shown in various stages of fabrication in FIGS. 13Athrough 13I and FIGS. 14A through 14I. The first and second metal levelsof the structure are to have a minimum photolithographic dimension of0.3 microns and a thickness of 0.6 microns. The third and fourth metallevels of the structure are to have a minimum photolithographicdimension of 0.7 micron and a metal thickness of 1.5 microns. Theinsulator thickness between the first and second metal levels as well asbetween the second and third metal levels is to be approximately 0.75microns. The insulator thickness between the third and fourth metallevels is to be approximately 1.5 microns thick. Each insulator layer isto be formed with a pore density of 40 percent voids.

Example for Process Scheme 1

FIGS. 13A through 13I illustrate an example of forming an ILD using thefirst process scheme. A mixture of low melting point glass particles andcarbon particles is deposited to form a first layer 1356, as shown inFIG. 13A. The carbon particles 1358 form about 40% of the mixture, andcorresponds generally to the desired pore density of 40% voids. One ofordinary skill in the art will understand, upon reading andcomprehending this disclosure, that the illustrated carbon particles arefor purposes of illustration only. The maximum particle size of thecarbon is about 0.6 microns. The first layer of the mixture is heatedsuch that the glass particles flow, resulting in a first insulator layerof carbon-containing glass that is 0.6 microns thick. The thickness ofthe glass generally corresponds to the maximum size of the carbonparticles.

Trenches 1360 (0.3 micron) are cut into the film 1356 in FIG. 13B. InFIG. 13C, the liner and copper layer 1362 are deposited and planarizedto form the metal layer. A capping layer 1364 is applied using a processas described by Farrar in the following commonly assigned U.S. patentapplication which is herein incorporated by reference in its entirety:“Method Of Fabricating A Barrier Layer On Top Surfaces Of Metals InDamascene Structures,” Ser. No. 09/534,224, filed on Mar. 24, 2000. Inthis process the capping layer remains only on the metal surface so thatthe upper surface of the intralayer dielectric is not covered.

A second layer 1366 of insulator slurry with a maximum carbon particle1368 of 1.35 microns is applied to form a carbon-containing 1.35 microninsulator layer, as shown in FIG. 13D. In FIG. 13E, the insulator layer1366 is etched to provide a dual damascene trench 1370A and 1370B forthe 0.6 micron second level metallurgy 1370A and the via structure 1370Bfor first to second level vias. As illustrated in FIG. 13F, the secondlevel metallurgy is deposited using a similar process to that used informing the first level metallurgy, so as to provide a liner and copperlayer 1372 and a capping layer 1374.

As illustrated in FIG. 13G, a third layer 1376 of insulating slurry witha maximum carbon particle 1378 size of 2.5 microns is deposited, forminga 2.5 micron insulator film. This insulator film is etched to form adual damascene trench and for the 1.5 micron thick third levelmetallurgy and the 0.75 micron second to third level vias. Asillustrated in FIG. 13H, the metallurgy is formed using a similarprocess as was used for the lower metal levels, so as to provide a linerand copper layer 1380 and a capping layer 1382.

As illustrated in FIG. 13I, a fourth layer 1384 of insulating slurrywith a maximum particle size of 3 microns is deposited, forming a 3micron insulator film. This insulator film is etched to form a dualdamascene structure for the 1.5 micron thick third level metallurgy andthe 1.5 micron third to fourth level vias. The metallurgy is formedusing a similar process as was used for the lower metal levels, so as toprovide a liner and copper layer 1386 and a capping layer 1388.

The carbon is removed by exposing the film to an oxygen-containingambient at an elevated temperature, resulting in CO₂ voids 1390 in theinsulator structure. In various embodiments, the elevated temperature isapproximately 450° C. In various embodiments, the elevated temperatureis within a range from 400 to 500° C. In various embodiments, theelevated temperature is within various subranges within the range from400 to 500° C. In each insulator level, the maximum particle size of thecarbon particles is equal to the thickness of the insulator film to beformed. Thus, there are many particles that will extend through the filmin each layer. Consequently, the diffusion distance of oxygen throughthe glass and between the carbon particles is minimal.

In various embodiments, a rapid thermal anneal (RTA) process is used tominimize the temperature exposure to the underlying device structure. Invarious embodiments, depending on the number of metal layers beingconstructed, it is desirable to perform one or more intermediate annealsto the partially completed structure to remove the carbon from the lowerlevels. These intermediate anneals shorten the diffusion path further.

A final passivation layer 1392 is capable of being built in a number ofprocesses depending upon specific system requirements. Variousembodiment use a 0.5 micron carbon glass layer 1394 which is depositedprior to the removal of the carbon in the lower composited films. Thecarbon is removed from this film at the same time as the rest of thestructure. A 4 micron layer of Polyimide 1396 is applied as the finalinsulating layer. Vias 1398 are formed in the composite layer so thatthe terminal metallurgy can be connected. In various embodiments, thevoids are formed by first etching the glass layer prior to the Polyimidelayer being applied. In various embodiments, the voids are formed afterthe Polyimide is applied. The use of a thin composite layer under thethick Polyimide (which is highly viscose when applied), ensures thatlittle if any Polyimide is able to fill the voids created between thefourth level metal lines.

Example for Process Scheme 2

FIGS. 14A through 14I illustrate an example of forming an ILD using thesecond process scheme. The following example assumes that the insulatorused has a density similar to SiO₂. As one of ordinary skill in the artwill understand, upon reading and comprehending this disclosure, theinsulator (such as glass) can have a different density and ion stoppingpower such that different implant energies are required. The requiredover pressure is dependent on the softening point of the glass as wellas the chosen annealing temperature.

In FIG. 14A, an insulator is deposited to form a 0.6 micron firstinsulator layer 1456. In various embodiments, the oxide is selected suchthat the softening point of the oxide is well below the melting point ofthe metal to be used for the conductors, and is preferably below 475 to500° C. If a high temperature metallurgy, such as tungsten, is used, thelimiting temperature is determined by the temperature that is compatiblewith the thermal budget of the device structure.

In FIG. 14B, trenches 1460 of 0.3 microns wide are etched into the oxideand the liner, copper metallurgy 1462 and capping layer 1464 are formedusing the same process as in the first example.

In various embodiments, two implants are performed. A first implant ofhelium has a dose of about 5×10¹⁵/cm² at an implant energy of about 10KEV. A second implant has a dose of about 5×10¹⁵/cm² at an implantenergy of about 45 KEV. These two implants provide sufficient helium(He) to form 40 percent voids with about a 50 percent excess helium toallow for over pressure and helium loss during processing. The structureis annealed using a RTA process at a temperature and for a timesufficient to form the voids 1490. In various embodiments, the annealingtemperature is within the range of 400 to 500° C. In variousembodiments, the annealing temperature includes various sub-rangeswithin the range of 400 to 500° C. During the void formation, the heightof the oxide spacers is increased by approximately 40%. After the voidsare formed most of the excess oxide is removed using a chemicalmechanical polishing (CMP) process. Sufficient oxide is left above themetal lines such that the capping layer is not removed during thepolishing.

In FIG. 14D, a layer 1466 of oxide approximately 0.75 microns thick isapplied followed by a touch-up CMP process to planarize the surface. Theprocess described above is implemented to form trenches 1470A for themetallurgy 1472 and trenches 1470B for the first to second level vias.In this case, the ion-implants are 7.510¹⁵/cm² at 25 KEV and 7.510¹⁵/cm²at 70 KEV. The structure is annealed at 400 to 500° C. untilapproximately 40% voids 1490 are formed. A CMP process is performed, asin the previous step.

In FIG. 14G, an oxide film approximately 0.6 microns thick is applied,and the sequence of steps used to form the first level of metal arerepeated to form the second level of metal 1480 and capping layer 1482as shown in FIG. 14H. An oxide film approximately 0.75 microns thick isapplied with processing similar to the first 0.75 micron film to formthe second to third level via structure.

In FIG. 14I, a 1.5 micron film 1484 is deposited and patterned to formthe troughs for the third metal level 1486 and capping layer 1488. Themetal is deposited and patterned using a process similar to that for thefirst two levels except for the greater metal thickness. Implants of7.510¹⁵/cm² at 45, 90, 170 and 280 KEV are performed, and the structureis annealed. The excess oxide is removed again leaving the capping layeron the metallurgy undisturbed. This process is repeated to form thethird to fourth level vias structures and the fourth metal level. Thefinal layer of oxide 1494 approximately 0.5 micron thick and thePolyimide layer 1496 are deposited and terminal vias 1498 are etched.

In this process sequence, a single damascene process is used in contrastto the dual damascene process used in the first process illustratedabove. A dual damascene process may exert too high a stress on the metallayers being formed because of the swelling which occurs during theformation of the vias. However, if the process to form the pores is runat a temperature sufficiently high, the glass flows sufficiently toprovide a low stress. Thus, in various embodiments which use arelatively low melting glass and a high temperature metal such astungsten, a dual damascene process is capable of being used.

System Level

FIG. 15 is a simplified block diagram of a high-level organization ofvarious embodiments of an electronic system according to the presentsubject matter. In various embodiments, the system 1500 is a computersystem, a process control system or other system that employs aprocessor and associated memory. The electronic system 1500 hasfunctional elements, including a processor or arithmetic/logic unit(ALU) 1502, a control unit 1504, a memory device unit 1506 and aninput/output (I/O) device 1508. Generally such an electronic system 1500will have a native set of instructions that specify operations to beperformed on data by the processor 1502 and other interactions betweenthe processor 1502, the memory device unit 1506 and the I/O devices1508. The control unit 1504 coordinates all operations of the processor1502, the memory device 1506 and the I/O devices 1508 by continuouslycycling through a set of operations that cause instructions to befetched from the memory device 1506 and executed. According to variousembodiments, the memory device 1506 includes, but is not limited to,random access memory (RAM) devices, read-only memory (ROM) devices, andperipheral devices such as a floppy disk drive and a compact disk CD-ROMdrive. As one of ordinary skill in the art will understand, upon readingand comprehending this disclosure, any of the illustrated electricalcomponents are capable of being fabricated to include a chip producedwith the low-K ILD in accordance with the present subject matter.

FIG. 16 is a simplified block diagram of a high-level organization ofvarious embodiments of an electronic system according to the presentsubject matter. The system 1600 includes a memory device 1602 which hasan array of memory cells 1604, address decoder 1606, row accesscircuitry 1608, column access circuitry 1610, control circuitry 1612 forcontrolling operations, and input/output circuitry 1614. The memorydevice 1602 further includes power circuitry 1616, a charge pump 1618for providing the higher-voltage programming pulses, and sensors 1620such as current sensors for determining whether a memory cell is in alow-threshold conducting state or in a high-threshold nonconductingstate. Also, as shown in FIG. 16, the system 1600 includes a processor1622, or memory controller for memory accessing. The memory device 1602receives control signals 1624 from the processor 1622 over wiring ormetallization lines. The memory device 1602 is used to store data whichis accessed via I/O lines. It will be appreciated by those skilled inthe art that additional circuitry and control signals can be provided,and that the memory device 1602 has been simplified to help focus on theinvention. At least one of the processor 1622 or memory device 1602 hasthe low-K ILD according to the present subject matter.

The illustration of system, as shown in FIG. 16, is intended to providea general understanding of one application for the structure andcircuitry of the present subject matter, and is not intended to serve asa complete description of all the elements and features of an electronicsystem using low-K ILD according to the present subject matter. As oneof ordinary skill in the art will understand, such an electronic systemcan be fabricated in single-package processing units, or even on asingle semiconductor chip, in order to reduce the communication timebetween the processor and the memory device.

Applications containing the low-K ILD as described in this disclosureinclude electronic systems for use in memory modules, device drivers,power modules, communication modems, processor modules, andapplication-specific modules, and may include multilayer, multichipmodules. Such circuitry can further be a subcomponent of a variety ofelectronic systems, such as a clock, a television, a cell phone, apersonal computer, an automobile, an industrial control system, anaircraft, and others.

CONCLUSION

The present subject mater relates to improved interlayer dielectric(ILD) devices and methods of formation. The present subject matterprovides methods for forming voids in the ILD after the metal layer hasbeen formed so as to alleviate the demands placed upon a process forproducing a porous structure. The present subject matter is particularlyuseful as photolithographic dimensions continue to decrease. In a firstscheme, the insulator is a multi-phase structure. After the insulator ispatterned, at least one of the phases is removed leaving the matrixphase intact. The intact matrix phase continues to provide structuralrigidity and the spaces where the second (or multiple phases in the caseof three phase or more complex structure) are now filled with air orother gas. A second process scheme introduces a gas phase (e.g. an inertgas such as helium (He), argon (Ar), or nitrogen (N₂)) into theinsulator after it is in the solid state. The introduced gas phase alsocan include air.

This disclosure refers to several figures that resemble flow diagrams.One of ordinary skill in the art will understand, upon reading andcomprehending this disclosure, that the methods related to the flowdiagrams may occur in the order as illustrated in the flow diagrams, andmay be ordered in another manner. Thus, the present subject matter isnot limited to a particular order or logical arrangement.

Although specific embodiments have been illustrated and describedherein, it will be appreciated by those of ordinary skill in the artthat any arrangement which is calculated to achieve the same purpose maybe substituted for the specific embodiments shown. This application isintended to cover adaptations or variations of the present subjectmatter. It is to be understood that the above description is intended tobe illustrative, and not restrictive. Combinations of the aboveembodiments, and other embodiments, will be apparent to those of skillin the art upon reviewing the above description. The scope of thepresent subject matter should be determined with reference to theappended claims, along with the full scope of equivalents to which suchclaims are entitled.

1. A method for forming an interlayer dielectric (ILD), comprising:forming an insulator layer, including forming an insulator with amultiphase structure, including forming a carbon-containing glass layer;forming at least one trench in the insulator layer; forming a metallayer in the at least one trench; and after forming the metal layer,forming voids in the insulator layer, including at least partiallyremoving at least one phase from the multiphase structure, includingexposing the carbon-containing glass layer to an oxygen (O₂) containingenvironment with an elevated temperature to form carbon dioxide (CO₂)voids.
 2. The method of claim 1, wherein: forming the insulator layer,forming the at least one trench in the insulator, and forming the metallayer in the at least one trench includes forming a structure with atleast a first insulator layer, a first metal layer, a second insulatorlayer, and a second metal layer; and forming voids in the insulatorlayer includes forming voids in the first insulator layer and the secondinsulator layer after the structure is formed.
 3. The method of claim 1,wherein: forming the insulator layer, forming the at least one trench inthe insulator, and forming the metal layer in the at least one trenchincludes forming a structure with at least a first insulator layer, afirst metal layer, a second insulator layer, and a second metal layer;and forming voids in the insulator layer includes: forming voids in thefirst insulator layer after forming the first insulator layer and thefirst metal layer of the structure and before forming the secondinsulator layer and the second metal layer of the structure; and formingvoids in the second insulator layer after forming the second insulatorlayer and the second metal of the structure.
 4. A method for forming aninterlayer dielectric (ILD), comprising: forming a multiphase matrix asan insulator layer, including forming glass with carbon particles;forming at least one trench in the insulator layer; fanning a metallayer in the at least one trench; and at least partially removing atleast one chase from the multiphase matrix to form voids in theinsulator layer, including exposing the insulator layer to an oxygen(O₂) containing environment at an elevated temperature to form carbondioxide (CO₂) voids in the insulator layer.
 5. A method for forming aninterlayer dielectric (ILD), comprising: forming a multiphase matrix asan insulator layer, including: mixing glass particles and carbonparticles; and heating the mixture to form a continuous matrix phasethat contains carbon particles; forming at least one trench in theinsulator layer; forming a metal layer in the at least one trench; andat least partially removing at least one phase from the multiphasematrix to form voids in the insulator layer, including exposing theinsulator layer to an oxygen (O₂) containing environment at an elevatedtemperature to form carbon dioxide (CO₂) voids in the insulator layer.6. The method of claim 5, wherein mixing glass particles and carbonparticles includes mixing fritted glass particles and graphiteparticles.
 7. A method for forming an interlayer dielectric (ILD),comprising: mixing glass particles and carbon particles; heating themixture to form a continuous matrix phase that contains carbonparticles; forming an insulator layer from the continuous matrix phase;forming at least one trench in the insulator layer; forming a metallayer in the at least one trench; and exposing the insulator layer to anoxygen (O₂) containing environment at an elevated temperature to formcarbon dioxide (CO₂) voids in the insulator layer.
 8. The method ofclaim 7, further comprising selecting a ratio of glass particles andcarbon particles to obtain a desired void density in the insulatorlayer.
 9. The method of claim 7, further comprising selecting a maximumparticle size of the carbon to obtain a desired insulator layerthickness.
 10. The method of claim 7, wherein the elevated temperatureis in a range between 400 and 500° C.
 11. The method of claim 7, whereinthe elevated temperature is supplied by laser pulse annealing.
 12. Themethod of claim 7, wherein the elevated temperature is supplied byplasma annealing.
 13. The method of claim 7, wherein exposing theinsulator layer to an oxygen (O₂) containing environment at an elevatedtemperature to form carbon dioxide (CO₂) voids in the insulator layerincludes selecting a time, a temperature, and an O₂ concentration tocontrol O₂ diffusion and CO₂ void formation.
 14. A method for forming aninterlayer dielectric (ILD), comprising: forming a first insulator layerusing a multiphase matrix; forming at least one trench in the firstinsulator layer; forming a first metal layer in the at least one trenchin the first insulator layer; forming a second insulator layer using amultiphase matrix; forming at least one trench in the second insulatorlayer; forming a second metal layer in the at least one trench in thesecond insulator layer; and after the second metal layer is formed, atleast partially removing at least one phase from the multiphase matrixto form voids in the first insulator layer and the second insulatorlayer, wherein: forming the first insulator layer and the secondinsulator layer includes: mixing glass particles and carbon particles;and heating the mixture to form a continuous matrix phase that containscarbon particles; and removing the at least one phase from themultiphase matrix includes exposing the multiphase matrix to an oxygen(O₂) containing environment at an elevated temperature to form carbondioxide (CO₂) voids.
 15. The method of claim 14, wherein the elevatedtemperature is in a range from 400 to 500° C.
 16. The method of claim14, further comprising performing a rapid thermal anneal (RTA) on themultiphase matrix to provide the elevated temperature.
 17. The method ofclaim 14, further comprising laser pulse annealing the multiphase matrixto provide the elevated temperature.
 18. The method of claim 14, furthercomprising plasma annealing the multiphase matrix to provide theelevated temperature.
 19. A method for forming an interlayer dielectric(ILD), comprising: forming a first insulator layer using a multiphasematrix; forming at least one trench in the first insulator layer;forming a first metal layer in the at least one trench in the firstinsulator layer; after the first metal layer is formed, at leastpartially removing at least one phase from the first insulator layer toform voids in the first insulator layer; forming a second insulatorlayer using a multiphase matrix; forming at least one trench in thesecond insulator layer; forming a second metal layer in the at least onetrench in the second insulator layer; and after the second metal layeris formed, at least partially removing at least one phase from thesecond insulator layer to form voids in the second insulator layer,wherein forming the first insulator layer and the second insulator layerincludes mixing glass particles and carbon particles and heating themixture to form a continuous matrix phase that contains carbonparticles, and removing the at least one phase from the multiphasematrix includes exposing the multiphase matrix to an oxygen (O₂)containing environment at an elevated temperature to form carbon dioxide(CO₂) voids.
 20. The method of claim 19, wherein the elevatedtemperature is in a range from 400 to 500° C.
 21. The method of claim19, further comprising performing a rapid thermal anneal (RTA) on themultiphase matrix to provide the elevated temperature.
 22. The method ofclaim 19, further comprising laser pulse annealing the multiphase matrixto provide the elevated temperature.
 23. The method of claim 19, furthercomprising plasma annealing the multiphase matrix to provide theelevated temperature.